Electrochemical Parameterization of Rhenium Redox Couples

Abstract

The observed rhenium potentials for ReIV/III, ReIII/II and ReII/I reversible couples, for mononuclear species, are analyzed in terms of the electrochemical parameterization scheme based upon the RuIII/II couples. Two independent sets of ReII/I potentials are observed, which, if extended, would cross the ReIII/II correlation line. The possible significance of these sets is explored. The ReIV/II couple correlation is roughly parallel to one of the ReII/ I correlation lines. The analysis leads to some interesting avenues for future synthetic studies.

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Document Details

Document Type
Technical Report
Publication Date
Feb 14, 1991
Accession Number
ADA232043

Entities

People

  • Alfred Beverley Philip Lever

Organizations

  • University of York

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Data Sets
  • Electrodes
  • Electrons
  • Engineering
  • Free Energy
  • Linear Regression Analysis
  • Materials
  • Materials Science
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  • Military Research
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Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Organic Chemistry
  • Regression Analysis.