Hydrogen Assisted Cracking and Corrosion of Some Highly Corrosion Resistant Alloys

Abstract

Project goals in this study focused on localized corrosion and hydrogen embrittlement. The former emphasized grain boundary and crevice corrosion. Research on the latter has improved understanding of the intrusion of hydrogen into metals and an improved capability of preventing hydrogen assisted cracking of structural members. Results have been obtained on hydrogen absorption from the gas phase using the scanning tunneling microscope (STM). These results, which characterize the absorption process at an atomic scale, provide the capability of STM for studying the H-material interaction. Another important advance is the development of a theoretical basis for hydrogen entry into a metal during cathodic charging from aqueous solution. Models enable previously unavailable parameters to be determined from steady state hydrogen permeation. As a result, application of the model can provide new diagnostic criteria for determining the role of various system parameters in modifying the rate of hydrogen entry.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1990
Accession Number
ADA233193

Entities

People

  • Howard W. Pickering

Organizations

  • Pennsylvania State University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alloys
  • Chemical Compounds
  • Chemical Engineering
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Corrosion
  • Diffusion
  • Embrittlement
  • Hydrogen Embrittlement
  • Material Degradation Processes
  • Materials
  • Materials Science
  • Mechanics
  • Metallurgy
  • Military Research
  • Solid Solutions

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.
  • Systems Analysis and Design