Effect of Electrode Material on SOCl2 Reduction

Abstract

A technologically important Li/SOCI2 electrochemical power source, exhibiting a high theoretical energy density, was discovered in the late 1960s and reduced to practice, for low discharge rates in the 1970s. A decade later a new requirement was imposed, that of maximizing its power density. To accomplish this, two design approaches were suggested: the construction of a module containing in-series connected thin cells, as one choice, and the employment of a flowing electrolyte, as the other. Seeking an improvement in performance in each of the proposed designs, modifications of both the electrode structure and composition were undertaken, unfortunately, with mixed results. Some of the difficulties were resolved through cell modeling.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1990
Accession Number
ADA234669

Entities

People

  • J. J. Smith
  • P. A. Mosier-boss
  • R. J. Nowak
  • S. Szpak

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Adsorption
  • Charge Transfer
  • Chemical Kinetics
  • Chemical Reactions
  • Controlled Atmospheres
  • Current Density
  • Desorption
  • Electrodes
  • Electrolytes
  • Electron Transfer
  • Electrons
  • Equations
  • Exchange Reactions
  • Kinetics
  • Materials
  • Spectra
  • Spectroscopy

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Plasma Physics.
  • Systems Analysis and Design