A Combined XPS-ISS-Modulated Molecular Beam Investigation of the Reactions of Oxygen and Fluorine with Silicon Surfaces

Abstract

The chemical reaction between Si(100) and molecular and atomic oxygen and fluorine has been studied. Using modulated molecular beam mass spectrometry, XPS and ISS, the kinetics of adsorption reaction and desorption have been studied in detail. Atomic fluorine and oxygen are much more reactive at high coverages than their molecular counterparts. At low coverages, this is true for O, but not for F.

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Document Details

Document Type
Technical Report
Publication Date
Feb 15, 1991
Accession Number
ADA234867

Entities

People

  • Thomas Engel

Organizations

  • University of Washington

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Adsorption
  • Chemical Reactions
  • Chemical Shifts
  • Chemistry
  • Decomposition
  • Desorption
  • Energy
  • Fluorides
  • Heat Of Activation
  • Kinetics
  • Mass Spectrometry
  • Measurement
  • Molecular Beams
  • Spectrometry
  • Spectroscopy
  • X Ray Photoelectron Spectroscopy
  • X Rays

Fields of Study

  • Chemistry
  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Molecular Photonics/Laser Physics