Preparation of Inorganic and Organometallic Polymers with Controlled Structures.

Abstract

Preparative and mechanistic aspects of polysilanes and polyphosphazenes are reviewed based on the several synthetic methods developed in the author's laboratories. Polysilanes are prepared by sonochemical reductive coupling, modifications and ring opening polymerization. Polyphosphazenes are prepared by the catalyzed polycondensation of phosphoranimines and by the direct reaction of phosphonites and phosphinites with silyl azides.

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Document Details

Document Type
Technical Report
Publication Date
May 02, 1991
Accession Number
ADA235359

Entities

People

  • Krzysztof Matyjaszewski

Organizations

  • Carnegie Mellon University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Advanced Materials
  • Block Copolymers
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Classification
  • Copolymers
  • Couplings
  • Crystal Structure
  • Films
  • Military Research
  • Polymeric Films
  • Polymerization
  • Polymers
  • Transition Temperature

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology