(Tertiary-butyl)cyclopentadienylindium(I), In(C5H4CMe3)-Synthesis, Characterization and X-Ray Structural Study
Abstract
The indium(I) compound, In(C5H4CMe3), has been prepared from the corresponding lithium cyclopentadienyl reagent Li(C5H4CMe3) and InC1 in OEt2. Characterization data have included partial elemental analyses (C,H), physical properties, IR, 1H NMR and mass spectroscopic data, oxidation reactions with dilute aqueous HC1 and a single-crystal X-ray structural study. The colorless crystal of In(C5H4CMe3) consists of infinite zigzag chains. There are no interstrand In...In interactions.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 14, 1991
- Accession Number
- ADA235576
Entities
People
- J. F. Lees
- O. T. Beachleyl Jr.
- Robin D. Rogers
Organizations
- University at Buffalo