Indium Compounds Which Contain Two Different Organic Substituents. Crystal Structure of (In(CH2CMe3)(CH2SiMe3)Cl)2, An Interesting Case of Partial Ligand Disorder in the Solid State
Abstract
Three new indium compounds which contain two different organic substituents, In(CH2CMe3)(CH2SiMe3)Cl, In(CH2CMe3)(C6H5)Cl, and (Me3CCH2) (Me3SiCH2)InPEt2 have been prepared, purified and characterized. All compounds were characterized by partial elemental analysis (C, H and P as appropriate), cryoscopic molecular weight studies in benzene solution as well as NMR and IR spectroscopic studies. All compounds exist as dimeric molecules in solution. NMR spectral data were consistent with the presence of mixtures of cis and trans isomers in solution.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 31, 1991
- Accession Number
- ADA236730
Entities
People
- Charles H. Lake
- John D. Maloney
- Melvyn Rowen M.R. Churchill
- O. T. Beachely Jr.
Organizations
- University at Buffalo