Mass Spectrometric Characterization of N,N-bis(2,4,6-Trichlorophenyl) urea.

Abstract

The title compound, an environmentally persistent contaminant of estuarine sediments, has been characterized by direct exposure desorption mass spectrometry. Under electron impact and positive chemical ionization conditions fragmentation to trichloroanilinium species was the predominant process, and the respective molecular ion species were less abundant. In methane enhanced negative chemical ionization mass spectrometry the predominant process was loss of hydrogen and chlorine from the molecular anion. Relative abundances of the molecular ion species in the two chemical ionization modes were similar.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1991
Accession Number
ADA239959

Entities

People

  • Elizabeth P. Burrows

Organizations

  • United States Army Biological Warfare Laboratories

Tags

DTIC Thesaurus Topics

  • Biomedical Research
  • Chlorine
  • Classification
  • Electrons
  • Environmental Monitoring
  • Hydrogen
  • Instrumentation
  • Ionization
  • Mass Spectra
  • Mass Spectrometers
  • Mass Spectrometry
  • Pyrolysis
  • Security
  • Spectra
  • Spectrometers
  • Spectrometry
  • Spectroscopy

Fields of Study

  • Chemistry
  • Environmental science

Readers

  • Combustion science or combustion engineering.
  • Molecular and Cellular Biochemistry

Technology Areas

  • Microelectronics