Corrosion of Aluminium Alloys by IRFNA

Abstract

Corrosion rate and related data have been obtained for 2014(3L65) aluminium alloy, either untreated or subjected to certain surface pre- treatments, before contact with IRFNA, gelled IRFNA (IRFNA + SiO2 + LiNO3) and these media containing added P2O5. The temperature dependence of the corrosion reaction in gelled IRFNA has also been studied electrochemically, using a 20 C temperature cycle. Similar temperature cycling data involving IRFNA were presented in the First Interim Report. The lowest corrosion rates determined by weight change occurred when the allow had been pre-treated with gaseous C1F3 before immersion in gelled IRFNA or gelled IRFNA containing 0.5 wt.% P2O5. The latter medium gave a low corrosion rate even in the absence of the C1F3 pre- treatment. Pre-treatment with a gaseous HF/F2 mixture or by electropolishing and anodising, before immersion in gelled IRFNA, conferred no advantage as judged electrochemically but these pre-treatments were not evaluated by weight change.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1991
Accession Number
ADA240807

Entities

People

  • Jeremy P. Mauger
  • Michael F. Dove
  • Norman Logan

Organizations

  • University of Nottingham

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aluminum Alloys
  • Auger Electron Spectroscopy
  • Auger Electrons
  • Body Weight
  • Chemical Synthesis
  • Chemistry
  • Electrochemistry
  • Electrodes
  • Electron Spectroscopy
  • Electrons
  • Heat Of Activation
  • Materials
  • Nitric Acid
  • Rocket Oxidizers
  • Spectroscopy
  • X Ray Photoelectron Spectroscopy
  • X Rays

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Surface Engineering/Surface Coating Technology.