Blistering of Graphite/Polymer Composites Galvanically Coupled with Metals in Sea Water

Abstract

The electrochemical nature of blistering in carbon vinyl ester composites in sea water and saline solution was confirmed. Carbon fiber/ polyester composites also blistered. It was therefore shown that blistering is a generic degradation phenomena for many carbon containing polymer composites. The location of the fluid filled blisters in the composites was detailed. The aqueous blister liquid contains organic species and has a pH greater than 10. Blisters formed on vinyl ester/platinum composites caused degradation of the polymer which could not be duplicated in 10N sodium hydroxide solution. Absorption kinetics data for water and electrolyte in carbon fiber/vinyl ester composites is established.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1991
Accession Number
ADA242861

Entities

People

  • Richard Brown
  • Shravan Miriyala
  • Thomas J. Rockett
  • Wayne C. Tucker

Organizations

  • University of Rhode Island

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alcohols
  • Body Weight
  • Carbon Fibers
  • Chemistry
  • Composite Materials
  • Glass Fibers
  • Graphitic Materials
  • Liquid Chromatography
  • Material Degradation Processes
  • Materials
  • Materials Laboratories
  • Materials Science
  • Polymer Degradation
  • Polymer Matrix Composites
  • Polymeric Films
  • Polymers
  • Spectra

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Polymer Science and Engineering.
  • Reinforced Composite Materials