Thermally Regenerative Fuel Cells

Abstract

The three phase project was undertaken to investigate solventless ionic liquids as possible working fluids for a new type of thermally regenerative fuel cell (TRFC). The heart of the new device, invented at Hughes Aircraft Company in 1983, is an electrochemical concentration cell where acid and base streams react to produce electrical energy. Thermal energy is then used to decompose the resulting salts and regenerate the cell reactants. In principle, a TRFC can be matched to any source of thermal energy simply by selecting working fluids with the appropriate regeneration temperature. However, aqueous working fluids (the focus of previous studies) impose limitations on both the operating temperatures and the achievable energy densities. It was the need to overcome these limitations that prompted the present investigation. Specific aims were to identify possible working fluids for TRFC systems with both low and high regeneration temperatures. A major advantage of our aqueous- fluid TRFC systems has been the ability to use hydrogen electrodes. The low activation and mass transfer losses of these electrodes contribute substantially to overall system efficiency.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1991
Accession Number
ADA242900

Entities

People

  • A. Kindler
  • F. A. Ludwig
  • J. Mchardy

Organizations

  • Hughes Aircraft Company

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Cell Membrane
  • Cells
  • Controlled Atmospheres
  • Decomposition
  • Electric Power
  • Energy
  • Fluids
  • Fuel Cells
  • Gases
  • High Temperature
  • Hydrogen
  • Ionic Liquids
  • Lewis Acids
  • Literature Surveys
  • Materials
  • Materials Science
  • Regenerative Fuel Cells

Readers

  • Electrical Engineering
  • Electrochemical Surface Science
  • Polymer Science and Engineering.

Technology Areas

  • Biotechnology