Lithographic Micropatterning of Polythiophene Thin-Films.

Abstract

Several semiconductor processing procedures that could be used to micropattern polythiophene thin-films were investigated. Using standard semiconductor lithographic processing procedures as a guide to what environments the polythiophene would be exposed to, a series of tests duplicating specific processing steps were devised. These tests determined that polythiophene could withstand heating on a hot plate to 150 C for 5 minutes, heating in a convection oven to 200 C for 30 minutes, and to 100 C for 1 hour without changing thin film thickness, index of refraction, surface morphology, or absorbance. Of the solvents polythiophene was exposed to, only isopropyl alcohol caused no film deformation. A reactive ion etching process using a low temperature silicate passivating and masking layer over the polythiophene is recommended for processing polythiophene. Using this procedure highly anisotropic structures were achieved using a 5 minute reactive ion etch with a chamber pressure of 50 mtorr, plasma power of 100 watts, and an oxygen flow rate of 50 standard cubic centimeters per minute.

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1991
Accession Number
ADA243819

Entities

People

  • Carl A. Kutsche

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Conductive Polymers
  • Films
  • Flow Rate
  • Low Temperature
  • Reactive Ion Etching
  • Refraction
  • Refractive Index
  • Semiconductors
  • Standards
  • Thin Films

Fields of Study

  • Materials science

Readers

  • Nanofabrication and Microfabrication.
  • Thermal Physics or Thermal Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene