The Effect of Jet Fuel Exposure on Advanced Aerospace Composites I: Thermal and Chemical Analysis

Abstract

The sensitivity of several aerospace composite materials to military jet engine fuel, JP-4, was investigated in this study. The effect of fuel on the physical and mechanical properties was evaluated. The absorption rates of JP-4 into the composites and the effects of JP-4 exposure on the mechanical properties of the composites were given in WRDC-TR-90-4064. Thermal analysis of the composite materials including TMA and DSC was performed and is reported here. During exposure to JP-4, the only composite materials that absorbed an appreciable amount of fuel were the APC-2 (+ or - 45)2S and HTA (+ or - 45)2S coupons. Chemical species desorbed from these composite specimens using a vacuum desorption apparatus developed in-house were analyzed using GC-MS and the results are reported here. As expected, HTA and APC-2 coupons tested at elevated temperatures after exposure to JP-4 had lower levels of the more volatile components of JP-4 than did the HTA and APC-2 coupons exposed to JP-4 and tested at room temperature. The more volatile components are more mobile and more likely to desorb from the polymer at elevated temperatures. APC-2 was found to have significant quantities of Phenol present. This is attributed to the slightly polar character of the poly-(aryl ether ether ketone) (PEEK) matrix thermoplastic of APC-2.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1991
Accession Number
ADA246559

Entities

People

  • David B. Curliss

Organizations

  • Wright Laboratory

Tags

Communities of Interest

  • Biomedical
  • Space

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Aryl Ethers
  • Composite Materials
  • Desorption
  • Fuels
  • Glass Transition Temperature
  • Jet Engine Fuels
  • Jet Engines
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • Mechanical Properties
  • Phase Transformations
  • Polymer Matrix Composites
  • Thermal Analysis
  • Thermoplastic Resins

Fields of Study

  • Materials science

Readers

  • Analytical Chemistry
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Reinforced Composite Materials

Technology Areas

  • Space
  • Space - Hall-Effect Thruster