Molecular Dynamics Calculations of Optical Nonlinear Properties of Materials

Abstract

The conductivity and nonlinear optical properties of small molecules beginning with the water molecule and further developed for hydrides and simple polymer molecules, including metal-ion containing polymers, are predicted based on ab initio techniques. These calculations are extended to the prediction, understanding, and improved design of polymer molecules for enhanced or controlled nonlinear properties. Specific predictions are provided for dipole polarizabilities and the first and second hyperpolarizabilities for small molecules. Nonlinear optical properties of small molecules. Ab initio calculations applied to polymers.

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Document Details

Document Type
Technical Report
Publication Date
Dec 20, 1991
Accession Number
ADA247095

Entities

People

  • J. E. Bloor

Organizations

  • University of Tennessee system

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Gaps
  • Band Structures
  • Chemical Synthesis
  • Chemistry
  • Computational Chemistry
  • Conduction Bands
  • Dielectric Gases
  • Energy Bands
  • First Principles Calculations
  • Materials
  • Materials Science
  • Molecules
  • Nitrogen Compounds
  • Optical Properties
  • Physical Chemistry
  • Small Molecules
  • Valence Bands

Fields of Study

  • Chemistry
  • Physics

Readers

  • Molecular Photonics/Laser Physics
  • Optical Physics and Photonics.
  • Polymer Science and Engineering.