Limiting Factors to Advancing Thermal Battery Technology for Naval Applications

Abstract

Thermal batteries are primary reserve electrochemical power sources using molten salt electrolyte which experience little effective aging while in storage or dormant deployment. Thermal batteries are primarily used in military applications, and are currently used in a wide variety of Navy devices such as missiles, torpedoes, decays, and training targets, usually as power supplies in guidance, propulsion, and Safe/Arm applications. Technology developments have increased the available energy and power density ratings by an order of magnitude in the last ten years. Present thermal batteries, using lithium anodes and metal sulfide cathodes, are capable of performing applications where only less rugged and more expensive silver oxide/zinc or silver/magnesium chloride seawater batteries could serve previously. Additionally, these batteries are capable of supplanting lithium/thionyl chloride reserve batteries in a variety of specifically optimized designs. Increases in thermal battery energy and power density capabilities are not projected to continue with the current available technology. Several battery designs are now at the edge of feasibility and safety. Since future naval systems are likely to require continued growth of battery energy and Power densities, there must be significant advances in battery technology. Specifically, anode alloy composition and new cathode materials must be investigated to allow for safe development and deployment of these high power, higher energy density batteries.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1991
Accession Number
ADA247773

Entities

People

  • Clinton S. Winchester
  • Patrick B. Davis

Organizations

  • Naval Surface Warfare Center

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Composite Materials
  • Current Density
  • Decomposition
  • Elements
  • Energy
  • Engineering
  • Failure Mode And Effect Analysis
  • Materials
  • Materials Science
  • Melting Point
  • Military Applications
  • Naval Warfare
  • Reliability
  • Surface Warfare
  • Thermal Batteries
  • Warfare

Fields of Study

  • Materials science

Readers

  • Economics
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Missile Defense Systems.