Intracellular Voltammetry at Ultrasmall Platinum Electrodes

Abstract

Ultrasmall platinum ring electrodes have been constructed by electrodeposition of platinum onto carbon ring electrodes. Electrodes thus formed show similar adsorption/desorption peaks for hydrogen and oxygen in 0.50 M H2SO4 solution compared to those obtained at conventional-sized electrodes. These electrodes have been used in conjunction with a technique involving linear scan voltammetry and subsequent cleaning pulses. In this technique, the applied potential is ramped anodically from an initial potential to a final potential, followed by a large positive potential to oxidatively clean the electrode and a large negative potential for electrode activation. Intracellular measurements of dopamine at platinum ring electrodes have been studied by integrated pulse linear scan voltammetry. In all experiments, minimal electrode fouling allows repeatable quantitative measurements to be carried out. Ultrasmall platinum electrodes, Electrodeposition.

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Document Details

Document Type
Technical Report
Publication Date
Dec 12, 1991
Accession Number
ADA248009

Entities

People

  • A. G. Ewing
  • D. K. Wong
  • G. Luo
  • Y. Y. Lau

Organizations

  • Pennsylvania State University

Tags

DTIC Thesaurus Topics

  • Adsorption
  • Carbon Fibers
  • Cells
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Coatings
  • Desorption
  • Dopamine
  • Electrodeposition
  • Electrodes
  • Hydrogen
  • Measurement
  • Metals
  • Micro-Machines
  • Neurons
  • Platinum

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Integrated Circuit Design and Technology.