Recognition of the Enantiomers of Chiral Organic Ammonium Salts by Chiral Dibenzyl- and Diphenyl-Substituted Diamido-or Dithionoamidopyridino-18- crown-6 Ligands

Abstract

New chiral pyridino-18-crown-6 ligands containing two amide, thionoamide or amine units and two benzyl or phenyl substituents on chiral macroring positions have been synthesized (see Figure 1). Some of these chiral ligands exhibit only moderate or no recognition for the enantiomers of (alpha- (1-naphthyl)ethyl)ammonium perchlorate as determined by 1H NMR spectral techniques.

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Document Details

Document Type
Technical Report
Publication Date
Mar 24, 1992
Accession Number
ADA248026

Entities

People

  • C. Y. Zhu
  • J. S. Bradshaw
  • P. Huszthy
  • Reed Izatt
  • Tianhong Wang

Organizations

  • Brigham Young University

Tags

DTIC Thesaurus Topics

  • Ammonium Perchlorate
  • Chemistry
  • Classification
  • Enantiomers
  • Free Energy
  • Identification
  • Military Research
  • Monitoring
  • Perchlorates
  • Recognition
  • Security

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry