Pulse Voltammetry in Single Cells Using Platinum Microelectrodes

Abstract

Multiple pulse voltammetry at platinum microelectrodes is described for intracellular measurements. In this technique, a sequence of three potential pulses is used for each current point measured. This pulse sequence provides a fixed cathodic activation potential and a fixed anodic cleaning potential before a varying detection potential, at which the current is measured. Voltammetric information is obtained by ramping the detection potential stepwise through the potential range of interest. The multiple pulse voltammetry technique has been applied to the study of the oxidation of potassium ferrocyanide, glucose and several catechols at platinum microdisk electrodes. In addition, this technique has been applied at ultrasmall platinum ring electrodes to reduce electrode fouling during intracellular voltammetry. In these in vivo experiments, the electrode response is degraded by only 30% after 40 minutes of intracellular multiple pulse. Voltammetry, Platinum electrodes, Intracellular measurements.

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Document Details

Document Type
Technical Report
Publication Date
Nov 22, 1991
Accession Number
ADA248080

Entities

People

  • A. G. Ewing
  • D. K. Wong
  • T. K. Chen
  • Y. Y. Lau

Organizations

  • Pennsylvania State University

Tags

DTIC Thesaurus Topics

  • Amino Acids
  • Calibration
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Detection
  • Electrodes
  • Liquid Chromatography
  • Measurement
  • Micro-Machines
  • Microelectrodes
  • Neurons
  • Oxidation
  • Platinum
  • Quantum Cascade Lasers
  • Sequences
  • Steady State

Readers

  • Electrochemical Surface Science