Rare Gas Clusters Containing Charged Atoms

Abstract

Three kinds of rare gas (R) containing clusters are considered in this article: (1) ionic clusters Rn+ and (R M)+, M being another atom or a molecule, (2) neutral rare gas-halogen n n clusters R n X with R X electron transfer, and (3) Rydberg excited R n clusters. These clusters have much in common, as all of them contain ions or ionic cores, with the positive charge delocalized mostly between some number of atoms. Such systems can be treated by the semiempirical diatomics-in-ionic-systems (DIIS) method. We present in this article a brief description of the DIIS method and the results of its applications to the kinds of clusters mentioned above. The article presents also discussions of results obtained by other theoretical methods and experimental studies.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1992
Accession Number
ADA248299

Entities

People

  • Isidore Last
  • Thomas F. George

Organizations

  • Washington State University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Atoms
  • Charged Particles
  • Chemistry
  • Diatomic Molecules
  • Dipole Moments
  • Electron Transfer
  • Ground State
  • Ionization
  • Ionization Potentials
  • Military Research
  • New York
  • Physics
  • Potential Energy
  • Quantum Chemistry
  • Quantum Properties
  • Spectra
  • Spin-Orbit Interaction

Readers

  • Molecular Photonics/Laser Physics
  • Quantum Chemistry
  • Systems Analysis and Design

Technology Areas

  • Microelectronics