Synthesis of Novel High Energy Density Materials Using Nitrocarbenes

Abstract

The objectives of this work which were fulfilled were to (1) use high level ab initio molecular orbital theory to predict the structures and energies of potential energetic molecules and to guide the synthesis of the more promising candidate molecules, (2) synthesize a number of potential molecules and provide samples to the Astronautics Laboratory for testing, and (3) modify existing polybutadiene binders and provide samples to the Astronautics Laboratory for testing. Several novel cyclopropenes were synthesized and are considered to be good candidates for novel high energy fuels.

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Document Details

Document Type
Technical Report
Publication Date
Feb 21, 1992
Accession Number
ADA248465

Entities

People

  • William P. Dailey

Organizations

  • University of Pennsylvania

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Cyclic Hydrocarbons
  • Energetic Materials
  • Fuels
  • Materials
  • Materials Laboratories
  • Materials Science
  • Molecules
  • Organic Chemistry
  • Polymers
  • Students
  • Universities

Fields of Study

  • Chemistry

Readers

  • Aerospace Test and Evaluation
  • Organic Chemistry
  • Quantum Chemistry

Technology Areas

  • Space