Chemistry of Polynitroethane Derivatives

Abstract

1,2-Difluorodinitroethylene was prepared by pyrolysis of 1,2- difluorotetranitroethane. Reactions of 1,1,-diiododinitroethylene with nucleophiles were studied. Nitrations of 1,1-diamino-2,2-dinitroethylenes gave trinitromethyl derivatives. Fluoride ion reacted with 1,1-diiododinitroethylene to give trifluorodinitroethane salts, used to prepare 3,3,3-trifluoro-2, 2dinitropropyl formal. Thermolysis of 1,1,2-tribromotrinitroethane gave 1,2-and 1,1-dibromodinitroethylene. 1,2-Difluorodinitroethylene, 1,2- diiododinitroethylene, Dibromodinitroethylene, 3,3,3-trifluoro-2,2- dinitropropanol, trinitromethyl compounds, Crystallography.

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Document Details

Document Type
Technical Report
Publication Date
Mar 31, 1992
Accession Number
ADA249264

Entities

People

  • Kurt Baum

Tags

Communities of Interest

  • Air Platforms
  • Counter IED
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkali Metals
  • Alkenes
  • Amines
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Classification
  • Contracts
  • Diffraction
  • Ethylenes
  • Fluorides
  • Materials Science
  • Military Research
  • Nitration
  • Organic Chemistry
  • Rocket Propellants
  • X-Ray Diffraction

Fields of Study

  • Chemistry

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  • Organic Chemistry