Vibrational Spectrum and Structure of 1,2-Dimethyl-1,2-disila-closo- dodecaborane

Abstract

The IR spectrum (thin film) of 1,2-dimethyl-1,2-disila-closo- dodecacarborane, DMSB, in the region 200 - 3600 cm-1 and its Raman spectrum (solid sample) in the region 5 - 3600 cm-1 are reported. It is concluded that the molecular bonding in DMSB is weaker than that in o-carborane. A Raman band at 399 cm-1 is tentatively assigned to the Si-Si bond.

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Document Details

Document Type
Technical Report
Publication Date
Apr 05, 1992
Accession Number
ADA250235

Entities

People

  • Dietmar Seyferth
  • L. A. Leites
  • Lars Wesemann
  • S. S. Bukalov

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • C4I

DTIC Thesaurus Topics

  • Argon Lasers
  • Chemistry
  • Films
  • Frequency
  • Frequency Bands
  • Ion Lasers
  • Massachusetts
  • Military Research
  • Raman Spectra
  • Raman Spectroscopy
  • Spectra
  • Spectroscopy
  • Thin Films
  • United States
  • United States Government
  • Vibrational Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Semiconductor Device Technology