Triplet Extinction Coefficients of Some Organic Compounds

Abstract

The triplet extinction coefficients 6T of acridine, anthracene, benzanthracene, dibenzanthracene, chrysene, pyrene, and pyrenecaroxaldehyde were measured at the visible spectral region at maximum triplet-triplet absorption. We used McClure's method together with cw lasers as excitation sources to obtain the ET values. Because these triplet extinction coefficients were measured with improved accuracy, we suggest that these compounds be used as standards. We wanted to compare the accuracy of our values with the ones suggested as tentative standards. Further, we tested the validity of McClure's method on anthracene by increasing the cw laser excitation intensities (power) Iex and recording triplet optical densities ODT. Under the experimental conditions we used, about 100 mW of cw laser power appears to be the upper limit. Triplet extinction coefficients of some organic compounds.

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Document Details

Document Type
Technical Report
Publication Date
May 24, 1992
Accession Number
ADA251034

Entities

People

  • Theodore G. Pavlopoulos

Organizations

  • Naval Command, Control and Ocean Surveillance Center

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Abstracts
  • Accuracy
  • Alcohols
  • Aromatic Polycyclic Hydrocarbons
  • Chemistry
  • Conversion Ratio
  • Ion Lasers
  • Laser Beams
  • Lasers
  • Light Sources
  • Measurement
  • Military Research
  • Organic Compounds
  • Spectra
  • Test And Evaluation

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers