Vibrational Overtone Spectroscopy of Gaseous Metallocenes

Abstract

The vibrational overtone spectra of ferrocene, acetylferrocene, ruthenocene and cyclopentadienyltitaniumtrichloride has been recorded in the third overtone region of the C-H stretch vibration. All of the spectra display four peaks in this region which, by comparison to the overtone spectrum of gaseous cyclopentadiene, appear where the C-H olefinic overtone vibration absorbs. The pattern of the absorption spectrum does not vary upon change of the metal (iron, ruthenium or titanium) or the ligand (chloride or acetylcyclopentadienyl).

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Document Details

Document Type
Technical Report
Publication Date
May 20, 1992
Accession Number
ADA251088

Entities

People

  • Cara Olsen
  • D. L. Snavely
  • S. Hassoon
  • T. Van Marter

Organizations

  • Bowling Green State University

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption Spectra
  • Chemical Compounds
  • Chemistry
  • Dye Lasers
  • Ferrocenes
  • Governments
  • Lasers
  • Liquid Dye Lasers
  • Metallocenes
  • Metals
  • Military Research
  • Spectra
  • Spectroscopy
  • Surface Warfare
  • Titanium Compounds
  • United States
  • Universities

Fields of Study

  • Chemistry

Readers

  • Molecular Photonics/Laser Physics
  • Organic Chemistry