Synthesis and Structural Characterization of New High-Valent Inorganic Fluorine Compounds and their Oxidizing Properties. Volume 1

Abstract

Noble gas fluorine oxidizers of Neon, Krypton, Argon, and Xenon have been synthesized and characterized. KrF(+) and XeF(+) cations have been made with neutral organic bases. Kr-N and Kr-O bonded molecules are also synthesized and characterized. The hypervalent compounds ClFsub6(-) and XeFsub5(-) are made. The anions IFsub6O(-), TeFsub6O(2-), TeFsub7(-) and TeFsub8(2-) anions are also made. Proof that the ClFsub6(-) anion exists is also presented. The photoelectron spectra of XeFsub2, XeFsub4, and XeFsub6 are obtained using monochromatized synchrotron radiation. The synthesis and characterization of Sb(OTeFsub5)sub6(-)Etsub4N(+), and Bi(OTeFsub5)sub6(-)Etsub4N(+) salts is completed. Radiotracer experiments involving (18)F are also accomplished to show the inability to synthesize NFsub5 is due to mainly steric reasons.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1992
Accession Number
ADA252840

Entities

People

  • G. J. Schrobilgen

Organizations

  • McMaster University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Diffraction
  • Electrons
  • Fluorine
  • Magnetic Resonance
  • Materials
  • Measurement
  • Noble Gases
  • Nuclear Spins
  • Quantum Properties
  • Spectra
  • Spectroscopy

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Pulsed Power and Plasma Physics.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene