Numerical Simulations of Spontaneous Ignition and Detonation in Propane-Air Mixtures

Abstract

The spontaneous ignition and subsequent detonation of propane-air mixtures caused by a weak shock in a partially confined volume containing an obstacle are studied using time-dependent numerical simulations. The motivation for this work is two-fold: first, to examine potential hazards from a leaking storage container (an obstacle to the flow), and second, to study the fundamental interaction of a shock wave with an obstacle in an energetic ambient gas. The numerical model combines a solution of the compressible equations of fluid dynamics with a phenomenological chemical induction model for species conversion and energy release. Nonreactive simulations show how the obstacle partially blocks the flow such that one portion of the shock front reflects off of the obstacle and another portion is transmitted. Reactive-flow simulations of stoichiometric propane-air mixtures show spontaneous ignition behind the shock reflected from the obstacle and later transition to detonation in the direction of the transmitted wave. Computations performed to study the effect of obstacle height show that different physical mechanisms are responsible for the transition to detonation for the various obstacle sizes considered. Simulations in a mixture with variable stoichiometry around the obstacle, a more realistic picture of the physical scenario, show decay of the transmitted shock and then re-ignition as the shock reaches the stoichiometric region. Two separate areas of ignition eventually combine and transition to detonation. As this detonation propagates into the lean region far from the obstacle, it decays into a shock wave followed by a decaying flame front.

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Document Details

Document Type
Technical Report
Publication Date
Jul 06, 1992
Accession Number
ADA252888

Entities

People

  • Carolyn R. Kaplan
  • Elaine Oran

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chemistry
  • Combustion
  • Computations
  • Detonations
  • Equations
  • Explosions
  • Fluid Dynamics
  • Ignition
  • Mach Number
  • Military Research
  • Reaction Mechanisms
  • Shock Waves
  • Simulations
  • Turbulent Mixing
  • Two Dimensional
  • Waves

Readers

  • Applied Combinatorial Optimization and Logic Circuit Design.
  • Combustion Dynamics and Shock Wave Physics.
  • Combustion science or combustion engineering.