Synthesis and Reactivity of Siloxide and Silamide Complexes Pertaining to Bond Breaking and Aggregation Phenomena

Abstract

The synthesis of siloxide and silamide complexes of tantalum has been carried out and their reactivity with respect to bond breaking and aggregation phenomena has been studied. Types of reactions include carbon monoxide cleavage to dicarbides and ketenylidene, carbon monoxide reduction, ketyl formation, ether cleavage, ligation of pyridine and related adducts, hydrocarbon activations, routes to early metal nitrides, and formation of cubic tantalum nitride.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1992
Accession Number
ADA254703

Entities

People

  • Peter T. Wolczanski

Organizations

  • Cornell University Department of Chemistry and Chemical Biology

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Alkanes
  • Carbon Monoxide
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Dielectric Gases
  • Electron Spin Resonance
  • Inorganic Chemistry
  • Low Temperature
  • Materials
  • Materials Science
  • Materials Testing
  • Organic Chemistry
  • Refractory Metals
  • Solid State Chemistry
  • Transition Metals

Fields of Study

  • Chemistry

Readers

  • Environmental Impact Assessment (EIA) of Proposed Air Force Base Actions.
  • Organic Chemistry
  • Surface Engineering/Surface Coating Technology.