Synthesis of Derivatives of Alpha, Omega Difunctional Perfluoroaliphatic Compounds for Low Dielectric Constant Resins
Abstract
Copper coupling reactions of perfluoroalkyl iodides with certain aryl iodides have been studied. Simple trial tests were carried out between perfluorooctyl iodide and idobenzene and between perfluorohexyl iodide and 4- odophenol. The desired product were obtained in good yield. However, the coupling of 1,6-diiodoperfluorohexane and 4-iodophenol gave a product which could not be isolated or purified. Protection of the phenolic OH by methylation or acetylation gave the coupled alpha, omega products in good yield.
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 06, 1992
- Accession Number
- ADA254928
Entities
People
- Robert L. Soulen
Organizations
- Southwestern University