The Synthesis of Chemiluminescent Flavoabzymes and Their Use in Metal Ion Detection.

Abstract

The ultimate goal of this research is to develop chemiluminescent (CL) abzymes and a technology for their use in metal ion detection. Four objectives must be reached in sequential order:.1st, a molecule (hapten) which resembles in space requirements an intermediate in a CL reaction must be synthesized; 2nd, a hapten protein conjugate (antigen) must be prepared and used to obtain monoclonal antibodies (Mab's); 3rd, one or more of the Mab's must catalyze the given CL reaction; and .4th , the hapten must be-modifiable such that the CL Mab's become specific complexers of metal ions. Accomplishment of the 1st objective would provide the first Mab mimic of bioluminescence. Attempts to synthesize a hapten to generate Cl flavoabzymes will be discussed as will progress in the synthesis of a hapten to be used to prepare abzymes to catalyze the CL reaction of H202 with oxalate esters Monoclonal antibodies (Mab's); Abzymes; hapten; antigen; chemiluminescence (CL); bioluminescence.

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Document Details

Document Type
Technical Report
Publication Date
Sep 02, 1992
Accession Number
ADA255567

Entities

People

  • Thomas C. Bruice

Organizations

  • University of California, Santa Barbara

Tags

DTIC Thesaurus Topics

  • Antibodies
  • Bioluminescence
  • Cell Line
  • Chemical Synthesis
  • Chemistry
  • Contracts
  • Detection
  • Laser Dyes
  • Materials
  • Methylation
  • Military Research
  • Molecules
  • Proteins
  • Rocket Oxidizers
  • Three Dimensional

Fields of Study

  • Chemistry

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Immunology
  • Organic Chemistry

Technology Areas

  • Space