The Titanium-Aluminum Phase Diagram. A Review of the Near Ti-50 At.% Al Phase Fields

Abstract

The understanding of the titanium-aluminum (Ti-Al) phase diagram is of great importance to the development of titanium-aluminide alloys and composites for high temperature applications. In this report, the Ti-Al phase diagram near 50 atomic percent (at.%) aluminum is critically reviewed. Murray's Ti-Al phase diagram has been well accepted by the materials community in the late 1980s. Recent results from solidification experiments point toward the existence of a high temperature alpha phase field consistent with two high temperature peritectic reactions (beta + L - alpha + L -* gamma) near 50 at.% aluminum. These reactions are not accounted for in Murray's Ti-Al phase diagram. Close evaluation of the past experimental techniques by which data were utilized in Murray's calculation of the Ti-Al phase diagram revealed areas of uncertainties. These uncertainties are primarily due to the limitation of analytical capabilities available at the time the experiments were performed.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1992
Accession Number
ADA255685

Entities

People

  • Ernest S. Chin
  • Ronald R. Biederman

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Alloys
  • Chemical Analysis
  • Chemistry
  • Crystal Structure
  • Ductility
  • Equations Of State
  • Heat Energy
  • Materials
  • Materials Science
  • Mechanical Properties
  • Metals
  • Phase Diagrams
  • Phase Transformations
  • Physical Properties
  • Thermodynamic Properties
  • Titanium Aluminide
  • X Rays

Fields of Study

  • Physics

Readers

  • Powder metallurgy of Titanium alloys.
  • Systems Analysis and Design