Analysis of the Absorption and Emission Spectra of Mn5+(3d2)in Sr5(PO4) 3Cl

Abstract

The absorption and emission spectra of Mn5+ (3d2) in Sr5(PO4)3C1 are analyzed using a C4 crystal-field Hamiltonian. The descent in symmetry from cubic was guided by it point-charge calculation of the crystal-field components. The calculated energy levels are in excellent agreement with those obtained experimentally. The resulting crystal-field parameters, Bnm, represent very well the crystal-field interactions of Mn5+ in Sr5(PO4)3C1. Mn5+, strontium chloroapatite, tunable lasers, absorption-emission spectra of Mn5+, spectroscopy of MnO4.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1992
Accession Number
ADA256619

Entities

People

  • Clyde A. Morrison
  • Guy Cormier
  • John A. Capobianco
  • Richard Moncorge

Organizations

  • Harry Diamond Laboratories

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Chemistry
  • Emission
  • Emission Spectra
  • Energy Levels
  • Experimental Data
  • Ground State
  • Lasers
  • Military Research
  • New York
  • Physics
  • Physics Laboratories
  • Quantum Properties
  • Spectra
  • Spin-Orbit Interaction
  • Symmetry

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition