Characterization of Explosives Processing Waste Decomposition Due to Composting

Abstract

Static pile and mechanically stirred composts generated at the Umatilla Army Depot Activity in a field composting optimization study were chemically and toxicologically characterized to provide data for the evaluation of composting efficiency to decontaminate and detoxify explosives-contaminated soil. Characterization included determination of explosives and 2,4,6- trinitrotoluene metabolites in composts and their EPA Synthetic Precipitation Leaching Procedure Leachates, leachate toxicity to Ceriodaphnia Dubia and mutagenicity of the leachates and organic solvent extracts of the composts to Ames bacterial strains TA-98 and TA-100. The main conclusion from this study is that composting can effectively reduce the concentrations of explosives and bacterial mutagenicity in explosives - contaminated so,- , and can reduce the aquatic toxicity of leachable compounds. Small levels of explosives and metabolites, bacterial mutagenicity, and leachable aquatic toxicity remain after composting. The ultimate fate If the biotransformed explosives, and the source(s) of residual toxicity and mutagenicity remain unknown. Toxicity; RAIII; Composting; Characterization; Chemistry; Decontamination.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1991
Accession Number
ADA257079

Entities

People

  • A. J. Stewart
  • C.-h. Ho
  • Elcin Tan
  • J. E. Caton
  • K. S. Ironside
  • R. L. Tyndall
  • W. H. Griest
  • W. M. Caldwell

Organizations

  • Oak Ridge National Laboratory

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Acetonitrile
  • Animals
  • Biomedical Research
  • Chemical Analysis
  • Chemical Synthesis
  • Chemistry
  • Decomposition
  • Drinking Water
  • Environmental Protection
  • Fish
  • Liquid Chromatography
  • Materials
  • Microorganisms
  • Mutagenicity Tests
  • Organic Solvents
  • Standards
  • Toxicity

Fields of Study

  • Environmental science

Readers

  • Agricultural Chemistry/Soil Science
  • Toxicology/Environmental Toxicology