Some Useful Bis(trimethylsilylamino)silanes (Preprint)

Abstract

For the preparation of cyclic silametallaazanes of type 1 in particular those in which R is a reactive substituent such as H or CH2=CH, we required the corresponding bis(trimethylsilylamino) silanes. Such compounds, we found, could be prepared readily by a Me3Si-for-H rearrangement reaction first reported by Wannagat and Niederprum in 1961.

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Document Details

Document Type
Technical Report
Publication Date
Nov 02, 1992
Accession Number
ADA258271

Entities

People

  • Dietmar Seyferth
  • Gerard Mignani

Organizations

  • Massachusetts Institute of Technology

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  • Chemistry

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