Cathodoluminescence Spectroscopy of Zinc Germanium Phosphide ZnGeP2

Abstract

Zinc Germanium Phosphide (ZnGeP2) is a nonlinear semiconductor suitable for use as a laser tuning element over the two to six micron wavelength range. Although this crystal has been studied in the past, its luminescent properties are not yet well understood. In this present study, ZnGeP2 has been examined using cathodoluminescence spectroscopy (CL). Specifically, the spectral dependence of the CL was obtained as a function of electron beam energy, beam current and temperature. The resulting CL was found to be polarized with a peak structure that was dependent on the polarization. This peak structure observed by CL is difficult to detect by photoluminescence (PL). It is believed that the- peaks are due to transitions between the conduction band and the spin orbit split acceptor level ALI. It is also believed that the excitation mechanism is in part responsible for the different structure observed.

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Document Details

Document Type
Technical Report
Publication Date
Dec 03, 1992
Accession Number
ADA258996

Entities

People

  • Michael R. Gregg

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Gaps
  • Band Structures
  • Band Theory Of Solids
  • Conduction Bands
  • Crystal Defects
  • Crystal Lattices
  • Crystals
  • Electrons
  • Energy Bands
  • Lasers
  • Optical Materials
  • Optical Properties
  • Optics
  • Quantum Mechanics
  • Semiconductors
  • Solid State Physics
  • Spectroscopy

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Optical Physics and Photonics.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics
  • Space