Spectroscopic and Structural Properties of Binuclear Platinum- Terpyridine Complexes
Abstract
Binuclear platinum-terpyridine (tpy) complexes have been prepared with a variety of bridging ligands resulting in a range of metal-metal distances (2.998(2) to 3.342(3) A). The energy of an intense visible absorption is strongly dependent on this metal-metal separation and is assigned to a d sigma *(Pt2) yield pi*(tpy) transition.
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 01, 1992
- Accession Number
- ADA259219
Entities
People
- Harry B. Gray
- James A. Bailey
- Vincent M. Miskowski
Organizations
- California Institute of Technology