A Study of Gas Phase Chemistry of Solid Propellant Ingredients Using a CO2 Laser

Abstract

This research program was designed to address the critical need for data on the gas-phase chemistry of solid propellants through the development and application of a microprobe mass spectrometer (MPMS) system. The MPMS system was used to study the gas-phase chemical reactions occurring above solid propellant ingredients and actual solid propellants when they are heated and/or ignited by the heat flux from a CO2 laser. In addition to the MPMS system direct and Schlieren photography were used to study the flame structure and twenty-five micron thermocouples were used to measure the gas-phase temperature profile. During the course of this research program, the majority of tests were performed with ammonium dinitramide (ADN), RDX, and an RDX based solid propellant, XM-39. In addition, preliminary studies of two fuel binders, HTPB and BAMO/NMMO, were performed. This report summarizes the experimental apparatus and the major findings for the oxidizers, ADN and RDX, and the solid propellant, XM-39.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1991
Accession Number
ADA259277

Entities

People

  • Thomas A. Litzinger

Organizations

  • Pennsylvania State University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Combustion
  • Composite Propellants
  • Computer Programming
  • Computer Programs
  • Computers
  • Data Acquisition
  • Data Processing
  • Data Processing Equipment
  • Ionization
  • Mass Spectrometers
  • Measurement
  • Processing Equipment
  • Propellants
  • Solid Propellants
  • Solid Rocket Oxidizers
  • Spreadsheet Software

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Rocket Propulsion.

Technology Areas

  • Directed Energy