Electrochemistry and Spectroelectrochemistry of Substituted Tetrabenzotriazporphine

Abstract

The spectral and electrochemical properties of tetrabenzo5,10, 15triazaporphine (TBTAP) and their magnesium derivatives, having a long alkyl chain attached to the meso-carbon have been studied. Both metal-free and metallated species show typical metal-free phthalocyanine-like spectra. Two reduction and two oxidation redox couples have been observed. The cation, anion, and dianion species of these porphyrin derivatives have been electrochemically generated and their electronic spectra are recorded.

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Document Details

Document Type
Technical Report
Publication Date
Jan 25, 1993
Accession Number
ADA260298

Entities

People

  • Alfred Beverley Philip Lever
  • Ankit Goel
  • C. C. Leznoff
  • J. E. Van Lier
  • Miao Hu
  • Y. H. Tse

Organizations

  • University of York

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Communities of Interest

  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Acetic Acid
  • Alcohols
  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Electrochemistry
  • Magnesium
  • Materials
  • Materials Science
  • Measurement
  • Metals
  • Military Research
  • Organic Chemistry
  • Oxidation
  • Plastic Explosives
  • Spectra
  • Spectrum Analyzers

Fields of Study

  • Chemistry

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  • Electrochemical Surface Science
  • Organic Chemistry

Technology Areas

  • Microelectronics