Intramolecular Bridge/Terminal Oxo Exchange within (MoV2O3)4+ Complexes Containing Linear Oxo Bridges

Abstract

Oxo complexes play a central role in the biological and inorganic chemistry of molybdenum. In the +5 oxidation state molybdenum oxo chemistry is dominated by the (Mo(V)2O3)(4+) unit, which contains a linear oxo bridge which spin pairs two d(1) centers while two terminal oxo ligands adopt syn or anti orientations perpendicular to the oxo bridge.

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Document Details

Document Type
Technical Report
Publication Date
Feb 15, 1993
Accession Number
ADA261230

Entities

People

  • N. J. Cooper
  • Robert L. Thompson
  • Samkeun Lee
  • Steven J. Geib

Organizations

  • University of Pittsburgh

Tags

Communities of Interest

  • Advanced Electronics
  • C4I
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Civil Engineering
  • Crystals
  • Diffraction
  • Exchange Reactions
  • Free Energy
  • Low Temperature
  • Molecular Orbital Theory
  • Molecular Structure
  • Resonance
  • Terminals
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.