Molecular Interactions and Properties with Many-Body Methods

Abstract

A variety of Air Force applications require highly detailed information about atoms, molecules, and their interactions. This information is necessary in problems ranging from chemical laser development, to the detection and identification of rocket plumes, to non-linear optics electron beam technology, and high density and energy fuels. The crucial component needed to understand molecular reactions is the potential energy surfaces (PES) that serve to describe the attractions among the atoms and molecules. However, such information is not easy to obtain. In many cases, the most direct approach to obtaining accurate potential surfaces for molecules, and detailed information about their excited states, vibrational spectra, and a wealth of other quantities, is high level ab initio solutions of the Schrodinger equation.

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Document Details

Document Type
Technical Report
Publication Date
Nov 30, 1992
Accession Number
ADA261688

Entities

People

  • Rodney J. Bartlett

Organizations

  • University of Florida

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Force
  • Chemical Lasers
  • Chemistry
  • Computational Chemistry
  • Computer Programs
  • Electron Beams
  • Electrons
  • Energy
  • Equations
  • First Principles Calculations
  • High Density
  • Molecules
  • Perturbation Theory
  • Potential Energy
  • Schrodinger Equation
  • Spectra
  • Vibrational Spectra

Fields of Study

  • Physics

Readers

  • Optical Physics and Photonics.
  • Quantum Chemistry
  • Theoretical Analysis.

Technology Areas

  • Directed Energy
  • Microelectronics