Tailored Organometallic Polymers

Abstract

Molecular tailoring concepts were applied to the synthesis of novel inorganic and organometallic polymers, many of them starting from commonly available polymorphs of SiO2 (beach sand). Liquid crystalline molecular order was identified in random co-oligomers and copolymers of bis(catecholato) spirosiloxanes. Factors affecting the nature and distribution of microstructural defects in liquid crystalline materials were identified, with a view to minimizing the scattering of light as it passes through such materials.... Organometallic polymers, Hypervalent silicon, High temperature, Liquid crystalline, Non-linear optical.

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Document Details

Document Type
Technical Report
Publication Date
Jan 31, 1993
Accession Number
ADA262446

Entities

People

  • Christopher Viney
  • Richard M Laine
  • Robert J. Corriu

Organizations

  • University of Michigan

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Analysis
  • Chemical Compounds
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Materials
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Materials Testing
  • Measurement
  • Optics
  • Organic Chemistry
  • Silicon Compounds

Fields of Study

  • Chemistry

Readers

  • Coastal Oceanography
  • Materials Science and Engineering.
  • Polymer Science and Technology

Technology Areas

  • Microelectronics