Metallization of Semiconducting Diamond: Mo, Mo/Au and Mo/Ni/Au

Abstract

A processing technology has been developed to make ohmic contacts to naturally doped semiconducting diamond. The approach follows, as far as possible, conventional photolithographic techniques for metallization of semiconductors currently in use in the microelectronic industry. Ohmic contacts have been successfully made to naturally doped semiconducting diamond using evaporated thin films of molybdenum, molybdenum/gold, and molybdenum/nickel/ gold. The metal contacts form a tenacious bond with the diamond substrate after annealing. The time and the temperature of annealing also affects the type and the degree of conduction of the contacts. Characterization of the interface of the metal contacts to diamond using AES, SIMS, RBS, XRD, SEM, and metallography clearly indicates that metal-carbide-precipitates nucleate and grow at the diamond/metal interface during annealing. It is concluded that the size and the areal density of the carbide precipitates at the interface are the principal factors that control the adhesion, and the mode and the degree of conductivity of the metal contacts.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1990
Accession Number
ADA262986

Entities

People

  • J. R. Zeidler
  • K. L. Moazed
  • M. J. Taylor

Organizations

  • Naval Command, Control and Ocean Surveillance Center

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Adhesion
  • Auger Electron Spectroscopy
  • Auger Electrons
  • Electrical Resistance
  • Electron Microscopy
  • Electron Spectroscopy
  • Films
  • Materials
  • Metal Contacts
  • Metal Films
  • Metal-Semiconductor Junctions
  • Metals
  • Molecular Orbital Theory
  • North Carolina
  • Resistance
  • Scanning Electron Microscopy
  • Spectroscopy

Fields of Study

  • Materials science

Readers

  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene