Explosive Consolidation of Combustion Synthesized TiC and TiB2: Precursor Morphology Effects

Abstract

The combustion synthesis/dynamic consolidation (CS/DC) technique has been applied to titanium-carbon and titanium-boron mixture with different initial precursor carbon and boron powder morphologies. The evolution of the CS/ DC product structure was investigated by analyzing and comparing the combustion synthesis products following three fabrication process steps: reacted loose powders, reacted green compacts, and reacted green compacts which were dynamically consolidated shortly after the synthesis. In all cases, the purity of the precursor carbon and boron powders was found to affect the products' residual porosity. However, the dependence of the resultant product grain morphology on the precursors' morphology was not as straightforward. Correlations between the respective product structures and possible reaction mechanisms are discussed.... SHS, Combustion synthesis, Explosive compaction, Dynamic consolidation, TiC, TiB2, Precursors, Morphology, Processing, Reaction mechanism.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1993
Accession Number
ADA263186

Entities

People

  • Andrus Niiler
  • Frederick B. Pierce
  • Laszlo J Kecskes
  • Sharon H. Robinson
  • Thomas Kottke

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Carbon Fibers
  • Ceramic Materials
  • Combustion
  • Crystal Structure
  • Crystals
  • Engineering
  • Explosives
  • Grain Growth
  • Grain Size
  • Heat Of Formation
  • Materials
  • Materials Processing
  • Materials Science
  • Measurement
  • Plastic Explosives
  • Reaction Mechanisms
  • Standards

Fields of Study

  • Materials science

Readers

  • Powder metallurgy of Titanium alloys.