An Evaluation of Factors Affecting the Solidification/Stabilization of Heavy Metal Sludge

Abstract

Solidification/stabilization of hazardous waste involves mixing the waste with a binder material to enhance the physical properties of the waste and to immobilize contaminants that may be detrimental to the environment. Many hazardous wastes contain materials that are known to inhibit the setting and strength development properties of cement and pozzolan binding agents commonly used in solidification/stabilization processes. This study presents the results of an evaluation into the effects of ten interfering substances (oil, grease, lead, copper, zinc, sodium hydroxide, sodium sulfate, phenol, trichloroethylene, and hexachlorobenzene) on the physical and contaminant mobility properties of a solidified/stabilized heavy metal sludge. Three binder materials (Portland cement, lime/fly ash, and cement/fly ash) were used to solidify/stabilize a synthetic metal plating waste sludge containing substantial concentrations of four metals (cadmium, chromium, nickel, and mercury). The effects of these interfering materials were evaluated using five physical tests: unconfined compressive strength (UCS), cone index, bulk density, wet/dry cycling, and permeability. Contaminant leaching properties were evaluated using the U.S. Environmental Protection Agency's Extraction Procedure test. Microchemical/ micromorphological analyses were also performed on the treated sludges.... Cement, Metals, Fixation, Pozzolan, Hazardous waste, Solidification, Heavy metals, Stabilization, Interferences.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1993
Accession Number
ADA264128

Entities

People

  • Larry W. Jones
  • R. M. Bricka

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Electron Microscopy
  • Environment
  • Environmental Pollutants
  • Environmental Protection
  • Fly Ash
  • Hazardous Waste
  • Heavy Metals
  • Materials
  • Materials Testing
  • Measurement
  • Phenols
  • Physical Properties
  • Sodium Hydroxide
  • Test Methods
  • Waste Products

Fields of Study

  • Materials science

Readers

  • Environmental Engineering.
  • Surface Engineering/Surface Coating Technology.