Improved Gallium Nitride and Aluminum Nitride Electronic Materials

Abstract

This report describes the progress in the second year of a three year program to improve the quality of gallium and aluminum nitride electronic materials. In this period we completed surface chemistry equipment modifications and characterization, and began experiments to control and understand the surface reactions associated with the growth of gallium nitride. By subjecting a physisorbed monolayer of trimethyl gallium (TMG) to a cool beam of atomic hydrogen atoms, we successfully converted it to metallic Ga, which is much more reactive with nitriding species, and will result in a more stoichiometric and higher purity gallium nitride. In the materials characterization effort of the program, infrared reflectance spectral and cathodoluminescence spectra were measured for epitaxial AIN films. The reflectance spectra were compared to a Lorentz oscillator model which make it possible to separate out the contribution of the AIN even when the bands of the film and substrate overlapped.

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Document Details

Document Type
Technical Report
Publication Date
Mar 25, 1993
Accession Number
ADA264570

Entities

People

  • C. C. Cheng
  • H. Gutleben
  • John Yates
  • Karl-heinz Bornschauer
  • M. L. Colaianni
  • P. J. Chen
  • R. P. Devaty
  • S. R. Lucas
  • W. D. Partlow
  • W. J. Choyke

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Aluminum Nitrides
  • Chemistry
  • Compound Semiconductors
  • Electronic Materials
  • Gallium Nitrides
  • Mass Spectroscopy
  • Materials
  • Materials Science
  • Measurement
  • Oscillators
  • Physics
  • Reflectance
  • Semiconductors
  • Silicon Carbide
  • Spectra
  • Surface Chemistry
  • Surface Properties

Fields of Study

  • Physics

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Semiconductor Device Technology
  • Spectroscopy.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene