Size Dependence of Chemical Reactivity of Gaseous Metal Clusters, A New Mechanistic Probe

Abstract

The determination of the mechanisms of chemical reactions leading to the formation of different types of materials is one of the principal occupations of many chemists today. To accomplish this, the dependence of the observed transformation is studied as a function of a number of intensive variables such as temperature, pressure, concentration of reactants as well as the Hydrogen ion concentration of the solution. In this account, we summarize recent studies in which the observed changes of the chemical reactivity of gaseous niobium clusters with size was used as a new degree of freedom that assists in deducing the mechanism of the chemical reactions studied.

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Document Details

Document Type
Technical Report
Publication Date
May 17, 1993
Accession Number
ADA264690

Entities

People

  • Mostafa El-Sayed

Organizations

  • University of California, Los Angeles

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • California
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Collisions
  • Dehydrogenation
  • Hydrogen
  • Hydrogenation
  • Intensity
  • Ionization
  • Ions
  • Mass Spectra
  • Military Research
  • Ph Factor
  • Protons
  • Reaction Mechanisms
  • Reactivities

Fields of Study

  • Chemistry

Readers

  • Quantum Chemistry
  • Surface Engineering/Surface Coating Technology.
  • Systems Analysis and Design