Probability of Alamethicin Conductance States Varies with Nonlamellar Tendency of Bilayer Phospholipids

Abstract

With few exceptions (1-3), membrane lipids are usually regarded as a kind of filler or passive solvent for membrane proteins. Yet, cells exquisitely control membrane composition. Many phospholipids found in plasma membrane bilayers favor packing into inverted hexagonal bulk phases (4-6). It was suggested that the strain of forcing such lipids into a bilayer may affect membrane protein function, such as the operation of trans-membrane channels (7- 10, 6). To investigate this, we have inserted the peptide alamethicin into bilayer membranes composed of lipids of empirically determined inverted hexagonal phase 'spontaneous radii' Ro, which will have expectably different degrees of strain when forced into bilayer form. We observe a correlation between measured Ro and the relative probabilities of different conductance states. States of higher conductance are more probable in Dioleoyl Phosphatidyl Ethanolamine (DOPE), the lipid of highest curvature, 1/Ro, than in Dioleoyl Phosphatidyl Choline (DOPC), the lipid of lowest curvature.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1993
Accession Number
ADA264957

Entities

People

  • A. M. Bezrukov
  • I. Vodyanoy
  • M. W. Tate
  • S. L. Keller
  • S. M. Gruner

Organizations

  • Princeton University

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Alkanes
  • Amino Acids
  • Cell Membrane
  • Curvature
  • Free Energy
  • Frequency
  • Geometry
  • Lipids
  • Magnetic Tape
  • Materials
  • Measurement
  • Membrane Lipids
  • Membrane Proteins
  • Military Research
  • Probability
  • Probability Distributions
  • Thickness

Fields of Study

  • Physics

Readers

  • Molecular and Cellular Biochemistry
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Structural Dynamics.