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Abstract

Electrochemical studies are carried out in three main areas. (1) Phthalocyanine electrochemistry: emphasis is placed on the chemistry of phthalocyanine modified electrodes for the study of electrocatalytic processes ultimately leading to chemical sensors. These studies include polymeric phthalocyanine conductive species. We also seek a comprehensive understanding of phthalocyanine electrochemistry to benefit all phthalocyanine redox applications. This work is extended to include Langmuir Blodgett (LB) surface (monolayer) phthalocyanine films with spectroelectrochemical studies being undertaken in situ on the trough surface. (2) Redox active ligands and electronic structure: A broad range of chemical techniques (uv/vis/FTIR/ resonance Raman/PES/ X-ray/Electrochemistry/solvatochromism/ ab initio calcs. are brought into play to understand the electronic structure, spectroscopy and electrochemistry of ruthenium (mainly) complexes of quinonoid ligands (including derivatives such as quinonediimines) where oxidation states are non-integral.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1993
Accession Number
ADA265136

Entities

People

  • Alfred Beverley Philip Lever

Organizations

  • University of York

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Detectors
  • Chemical Synthesis
  • Chemistry
  • Electrochemistry
  • Electrodes
  • Electron Transfer
  • Films
  • Hydrogen
  • Hydrogen Sulfides
  • New York
  • Organometallic Compounds
  • Oxidation
  • Phthalocyanines
  • Ruthenium
  • United States
  • United States Government

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Polymer Science and Technology
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Microelectronics