Hydrogen-Bond Polymorphs of Guanidinium 4-Biphenylsulfonate

Abstract

Hydrogen bonding is used to direct guanidinium sulfonates, C(NH2)3(+) RSO3(-), into specific molecular packing arrangements in the solid state. Guanidinium sulfonates frequently self-assemble into two-dimensional sheets formed by hydrogen bonds between the six guanidinium protons and the six sulfonate oxygen lone electron pairs. Guanidinium 4-biphenylsulfonate crystallizes hydrogen bonding patterns. We report on the synthesis of these polymorphs and their characterization by FTIR spectroscopy and single crystal X- ray diffraction.

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Document Details

Document Type
Technical Report
Publication Date
Apr 22, 1993
Accession Number
ADA265294

Entities

People

  • M. C. Etter
  • M. D. Ward
  • V. A. Russell

Organizations

  • University of Minnesota

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  • Weapons Technologies

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  • Chemical Synthesis
  • Chemistry
  • Classification
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  • Hydrogen Bonds
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  • Minnesota
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  • Organic Chemistry
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  • Single Crystals
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  • Chemistry

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Technology Areas

  • Microelectronics
  • Microelectronics - Graphene