Theory and Modeling of Thermal Reaction Propagation in Beam-Initiated Explosives

Abstract

Previous work on the thermal initiation of energetic materials by particle beams concentrated on uniformly irradiated confined samples. The present report extends the work to situations where only a portion of the material has been irradiated. In some materials (e.g., TATB) only the irradiated region undergoes thermal initiation; in other materials a thermal initiation front has been observed (by thermocouple response) to propagate away from the irradiated region. The frontal speeds are of the order of centimeters per second to tens of centimeters per second. These slow speeds eliminate the possibility of pressure propagation or a deflagration to detonation transition (DDT). Modeling is based on the interference that at the thermal initiation temperature the material develops a greatly enhance thermal and gaseous diffusivity. This allows the exothermic energy released to propagate into the cold region and forestalls any explosive temperature rise. At a well defined positive R* (the explosion radius) thermal initiation propagation ceases and an explosive temperature rise takes place.

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Document Details

Document Type
Technical Report
Publication Date
Jun 10, 1993
Accession Number
ADA266105

Entities

People

  • A. Stolovy
  • J. B. Aviles Jr.

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Boltzmann Equation
  • Chemical Reactions
  • Cold Regions
  • Decomposition
  • Diffusion
  • Directed Energy Weapons
  • Electron Beams
  • Energetic Materials
  • Exothermic Reactions
  • Experimental Data
  • Explosives
  • Particle Beam Weapons
  • Particle Beams
  • Thermal Conductivity
  • Thermal Diffusion
  • Thermal Diffusivity
  • Transport Properties

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Plasma Physics / Magnetohydrodynamics
  • Rocket Propulsion.

Technology Areas

  • Directed Energy