Amide and Tetrazene Complexes of Transition and Main Group Elements as Precursors for the Low Temperature Synthesis of Elemental Nitrides
Abstract
Tetrazene complexes and nitrene compounds derived therefrom were prepared. Attempts to use these compounds as precursors to metal nitride species failed. Metal acetylide complexes were prepared and examined by X-ray crystallography. Electrochemical procedures to deposit aluminum nitride films were explored using nonaqueous solvents. The reaction of several organometallics with azide ion was studied. The disproportionation reactions between 17-electron chromium triad radicals and various nucleophiles were characterized by infrared spectroscopy. The formation of reversible adducts from the reaction between trivalent phosphorus donor ligands and unsaturated organic carbonyl compounds was observed.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 01, 1993
- Accession Number
- ADA266246
Entities
People
- William C. Trogler
Organizations
- University of California, San Diego